| Person | Type | Job | Role(s) | Episodes |
|---|---|---|---|---|
 Hiroshi Nishikiori | Crew | Directing | Director | 74 |
 Kiyotaka Haimura | Crew | Writing | Writer | 48 |
 Youhei Suzuki | Crew | Directing | Assistant Director | 1 |
Hiroyuki Yoshino | Crew | Writing | Writer | 26 |
Masanao Akahoshi | Crew | Writing | Writer | 48 |
Shigeki Awai | Crew | Directing | Director | 1 |
Yuki Morita | Crew | Directing | Director | 1 |
Raku Nishikimi | Crew | Visual Effects | Animation Director | 2 |
Ryuuta Yanagi | Crew | Visual Effects | Supervising Animation Director | 24 |
Jiang Yong | Crew | Visual Effects | Animation Director | 1 |
Megu Otsubo | Crew | Visual Effects | Key Animation | 1 |
Chie Yoshimoto | Crew | Visual Effects | Key Animation | 2 |
 Akiko Hiramatsu | Cast | Actress | Vento of the Front (voice) | 1 |
 Ayako Kawasumi | Cast | Actress | Laura Stuart (voice) | 11 |
 Emi Shinohara | Cast | Actress | Misuzu Misaka (voice) | 5 |
 Hiroki Touchi | Cast | Actor | Acqua of the Back (voice) | 7 |
 Hochu Otsuka | Cast | Actor | Terra of the Left (voice) | 2 |
 Keiji Fujiwara | Cast | Actor | Amata Kihara (voice) | 4 |
 Kenji Nomura | Cast | Actor | Touya Kamijou (voice) | 7 |
 Kikuko Inoue | Cast | Actress | Shiina Kamijou (voice) | 5 |
 Kisho Taniyama | Cast | Actor | (voice) | 1 |
 Kohsuke Toriumi | Cast | Actor | Saiji Tatemiya (voice) | 12 |
 Mika Doi | Cast | Actress | Monaka Oyafune (voice) | 1 |
 Misato Fukuen | Cast | Actress | Maika Tsuchimikado (voice) | 9 |
 Norio Wakamoto | Cast | Actor | Biagio Busoni (voice) | 3 |
 Rei Sakuma | Cast | Actress | Lidvia Lorenzetti (voice) | 7 |
 Rie Kugimiya | Cast | Actress | Agnese Sanctis (voice) | 11 |
 Ryoka Yuzuki | Cast | Actress | Oriana Thomson (voice) | 8 |
 Takehito Koyasu | Cast | Actor | Commander of the Knights (voice) | 6 |
 Tomokazu Sugita | Cast | Actor | Aureolus Izzard (voice) | 2 |
 Toshihiko Seki | Cast | Actor | Aleister Crowley (voice) | 9 |
 Yoko Honna | Cast | Actress | Vasilisa (voice) | 1 |
 Yuriko Yamaguchi | Cast | Actress | Himegami's Mother (voice) | 1 |
 Yoko Soumi | Cast | Actress | Elizard (voice) | 4 |
 Akeno Watanabe | Cast | Actress | Sherry Cromwell (voice) | 10 |
 Ami Koshimizu | Cast | Actress | Shizuri Mugino (voice) | 3 |
 Ayumi Fujimura | Cast | Actress | Seiri Fukiyose (voice) | 10 |
 Daisuke Kishio | Cast | Actor | Mitsuki Unabara (voice) | 6 |
 Kenji Nojima | Cast | Actor | Man on the Phone (voice) | 1 |
 Kenta Miyake | Cast | Actor | Ritoku Komaba (voice) | 2 |
 Mamiko Noto | Cast | Actress | Aisa Himegami (voice) | 19 |
 Masafumi Kimura | Cast | Actor | Pope (voice) | 1 |
 Rina Sato | Cast | Actress | Mikoto Misaka (voice) | 74 |
 Ryuusaku Chijiwa | Cast | Actor | Doctor (voice) | 1 |
 Satoshi Hino | Cast | Actor | Shiage Hamazura (voice) | 27 |
 Yoshihisa Kawahara | Cast | Actor | Skill-Out (voice) | 1 |
 Yuka Terasaki | Cast | Actress | Sasha Kreutzev (voice) | 4 |
 Yutaka Nakano | Cast | Actor | Frog-Faced Doctor (voice) | 13 |
 Aki Toyosaki | Cast | Actress | Kazari Uiharu (voice) | 8 |
 Anri Katsu | Cast | Actor | Motoharu Tsuchimikado (voice) | 55 |
 Ao Takahashi | Cast | Actress | Researcher (voice) | 1 |
 Aya Endo | Cast | Actress | Orsola Aquinas (voice) | 12 |
 Harumi Sakurai | Cast | Actress | Awaki Musujime (voice) | 7 |
 Hiromu Miyazaki | Cast | Actor | Rod (voice) | 1 |
 Kana Asumi | Cast | Actress | Hyouka Kazakiri (voice) | 7 |
 Kei Shindo | Cast | Actress | Carissa (voice) | 4 |
 Mariya Ise | Cast | Actress | Lucia (voice) | 8 |
 Megumi Takamoto | Cast | Actress | Female Student (voice) | 1 |
 Minako Kotobuki | Cast | Actress | Mitsuko Kongou (voice) | 1 |
 Nobuhiko Okamoto | Cast | Actor | Accelerator (voice) | 74 |
 Rina Hidaka | Cast | Actress | Last Order (voice) | 13 |
 Satomi Arai | Cast | Actress | Kuroko Shirai (voice) | 50 |
 Shiori Izawa | Cast | Actress | Girl in the Dress (voice) | 2 |
 Yuka Iguchi | Cast | Actress | Index (voice) | 74 |
 Mai Fuchigami | Cast | Actress | Agata (voice) | 1 |
 Yumi Hara | Cast | Actress | Suama Oyafune (voice) | 1 |
 Ai Kayano | Cast | Actress | Announcer (voice) | 1 |
 Aya Suzaki | Cast | Actress | Rikou Takitsubo (voice) | 2 |
 Chinatsu Akasaki | Cast | Actress | Saiai Kinuhata (voice) | 2 |
 Hitomi Yoshida | Cast | Actress | Judgment (voice) | 1 |
 Maaya Uchida | Cast | Actress | Frenda Seivelun (voice) | 3 |
 Genki Muro | Cast | Actor | Knight (voice) | 1 |
 Mari Hino | Cast | Actress | Riméa (voice) | 3 |
 Sayaka Harada | Cast | Actress | Villian (voice) | 5 |
 Toshiyuki Morikawa | Cast | Actor | Fiamma of the Right (voice) | 2 |
 Shizuka Itoh | Cast | Actress | Kaori Kanzaki (voice) | 55 |
 Tatsuhisa Suzuki | Cast | Actor | Amai Ao (voice) | 2 |
 Jouji Nakata | Cast | Actor | Ouma Yamisaka (voice) | 1 |
 Kimiko Koyama | Cast | Actress | Komoe Tsukiyomi (voice) | 1 |
 Yasuaki Takumi | Cast | Actor | Skill-Out (voice) | 1 |
 Masaya Matsukaze | Cast | Actor | Kakine-teitoku (voice) | 3 |
Shizuka Okohira | Cast | Actress | Dormitory Superintendent (voice) | 2 |
 Shun Takagi | Cast | Actor | Anti-Skill (voice) | 2 |
 Juri Kimura | Cast | Actress | Flight Attendant (voice) | 1 |
 Yuuki Takada | Cast | Actress | Lessar (voice) | 3 |
 Atsushi Abe | Cast | Actor | Touma Kamijou (voice) | 74 |
 Minori Suzuki | Cast | Actress | Floris (voice) | 4 |
 Hiroo Sasaki | Cast | Actor | Skill-Out (voice) | 1 |
 Miho Okasaki | Cast | Actress | Citizen (voice) | 1 |
 Hiroko Ushida | Cast | Actress | Nancy (voice) | 1 |
 Eri Yukimura | Cast | Actress | Tsushima (voice) | 5 |
 Hitomi Ohwada | Cast | Actress | Xochitl (voice) | 1 |
 Natsumi Fujiwara | Cast | Actress | Bayloupe (voice) | 2 |
 Rika Abe | Cast | Actress | Clerk (voice) | 1 |
 Hiroki Maeda | Cast | Actor | Knight (voice) | 1 |
 Chitose Morinaga | Cast | Actress | Megumi Teshio (voice) | 1 |
 Kouichi Souma | Cast | Actor | Citizen (voice) | 1 |
 Ryo Sugisaki | Cast | Actor | Doctor (voice) | 1 |
 Yuya Murakami | Cast | Actor | Maintenance Personnel (voice) | 1 |
 Nana Hamasaki | Cast | Actress | Smartvery (voice) | 2 |
 Ryota Suzuki | Cast | Actor | Customer (voice) | 1 |
 Takahiro Shimada | Cast | Actor | Eiker Lugoni (voice) | 1 |
 Makoto Sahara | Cast | Actor | Taxi Driver (voice) | 2 |
 Sho Nogami | Cast | Actor | Management (voice) | 1 |
 Jun Kasama | Cast | Actor | Pilot (voice) | 1 |
Syouhei Yamaguchi | Cast | Actor | Amakusa-Style Boy (voice) | 1 |
 Azusa Kataoka | Cast | Actress | Angelene (voice) | 7 |
 Daisuke Takahashi | Cast | Actor | Saraku (voice) | 1 |
 Yuuki Hirose | Cast | Actress | Sister (voice) | 1 |
 Ayaka Shimizu | Cast | Actress | Engineer (voice) | 1 |
 Hiromichi Tezuka | Cast | Actor | Roman Orthodox Man (voice) | 1 |
 Sayumi Watabe | Cast | Actress | Announcer (voice) | 1 |
 Kensuke Sato | Cast | Actor | Roman Orthodox Man (voice) | 1 |
 Rui Tanabe | Cast | Actress | Lancis (voice) | 2 |
 Aira Yuuki | Cast | Actress | Amakusa-Style Girl (voice) | 1 |
 Daichi Hayashi | Cast | Actor | Baba (voice) | 1 |
 Hinata Tadokoro | Cast | Actor | Citizen (voice) | 1 |
 Yu Sasahara | Cast | Actress | Citizen (voice) | 1 |
 Nozomi Sasaki | Cast | Actress | Misaka 10032 (voice) | 5 |
 Gen Sato | Cast | Actor | Knight (voice) | 1 |
Asuka Minamori | Cast | Actress | Doctor (voice) | 1 |
 Taro Kiuchi | Cast | Actor | Chimitsu Sunazara (voice) | 2 |
 Ryunosuke Watanuki | Cast | Actor | Customer (voice) | 1 |
 Kaito Takeda | Cast | Actor | Customer (voice) | 1 |
 Eiichiro Tokumoto | Cast | Actor | Musset (voice) | 1 |
 Yuna Ogata | Cast | Actress | Citizen (voice) | 1 |
 Kōsuke Katayama | Cast | Actor | Convoy Driver (voice) | 1 |
 Ken Mizukoshi | Cast | Actor | Tatsuhiko Saku (voice) | 1 |
 Hayato Kimura | Cast | Actor | Deputy Pilot (voice) | 1 |
 Yu Akiba | Cast | Actor | Citizen (voice) | 1 |
 Tomoko Tsuzuki | Cast | Actress | Tetsumou (voice) | 1 |
 Hideki Kojima | Cast | Actor | Mike (voice) | 1 |
Daisuke Matsuo | Cast | Actor | Skill-Out (voice) | 1 |
Masahide Yamaguchi | Cast | Actor | Male Student (voice) | 1 |
Mitsuru Takakuwa | Cast | Clerk (voice) | 1 | |
 Rinko Hayashi | Cast | Actress | Landlady (voice) | 1 |
 Yuuka Nakatsukasa | Cast | Actress | Girl (voice) | 1 |
 Takeru Kikuchi | Cast | Actor | Kouyagi (voice) | 3 |
Ai Ikeda | Cast | High School Girl (voice) | 1 | |
Ryusuke Fujimoto | Cast | Male Student (voice) | 1 | |
Toratarō | Cast | Sphynx (voice) | 17 | |
Takuya Ōshio | Cast | Anti-Skill (voice) | 1 | |
Masahiro Kono | Cast | Actor | Delinquent (voice) | 1 |
 Masaki Nakanishi | Cast | Actor | Citizen (voice) | 1 |
| Person | Type | Job | Role(s) | Episodes |
